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CLADDING · BIMETAL PRODUCT · BIMETAL PRESSURE VESSEL TECHNICAL STUDY

Development of Sintered Flux for High-Speed Strip Cladding

Literature Overview and Research Background

Strip cladding, particularly electroslag welding (ESW) and submerged arc welding (SAW) using strip electrodes, has become the dominant method for producing large-area clad plates used in pressure vessels, heat exchangers, and corrosion-resistant linings. The flux in strip cladding serves multiple critical functions: slag formation, arc stabilization, alloying of the weld deposit, and protection of the molten pool from atmospheric contamination. This literature study examines the development of a sintered flux specifically designed for high-speed strip cladding operations, addressing the challenges of maintaining consistent weld quality at increased travel speeds while ensuring adequate alloy transfer and slag properties.

The research context is driven by the industry demand for higher productivity in clad plate manufacturing. Conventional strip cladding speeds of 200-400 mm/min are being pushed toward 600-800 mm/min, which imposes severe demands on flux performance: the slag must solidify quickly enough to support the weld pool, yet remain fluid enough to ensure proper arc stability and alloy pickup.

Core Technical Findings

Flux Composition Design

The developed sintered flux employs a fluorite-silicate system with controlled basicity and alloying additions. The compositional design follows a systematic approach based on the following principles:

Component Typical Range (wt%) Function
SiO2 25-35 Slag viscosity control, deoxidation
CaF2 30-40 Arc stabilization, slag fluidity
CaCO3 10-15 Slag foaming, alloy pickup
MnO 5-10 Alloy transfer to deposit
Fe2O3 2-5 Alloy transfer, slag viscosity
TiO2 3-8 Slag viscosity, arc stability
Al2O3 2-5 Slag viscosity, arc stability
SiC 1-3 Deoxidation, carbon control
Alloy powder (Cr, Ni, Mo) 5-15 Controlled alloy transfer to deposit

The basicity (R = CaO/SiO2) is maintained in the range of 1.0-1.5, which provides optimal slag fluidity for high-speed welding while ensuring adequate slag cover thickness to protect the weld pool.

Performance at High Speed

The critical finding of this study is that the developed flux maintains consistent weld quality at travel speeds up to 800 mm/min, compared to 400-500 mm/min for conventional fluxes. This is achieved through:

  1. Rapid slag solidification kinetics — The fluorite-silicate system with controlled TiO2 content produces a slag that solidifies within 0.5-1.0 seconds after the arc passes, providing immediate mechanical support to the solidifying weld metal.
  2. Stable arc characteristics — The CaF2 content ensures a stable, narrow arc with minimal arc wander, even at high travel speeds where the arc-to-weld geometry becomes increasingly asymmetric.
  3. Controlled alloy transfer — The flux contains pre-mixed alloy powder (Cr, Ni, Mo) that dissolves into the slag and transfers to the weld deposit, compensating for the reduced residence time of the molten pool at high speeds.
  4. Low hydrogen pickup — The sintered flux, being a dry, porous material with controlled moisture content (<0.5%), minimizes hydrogen absorption, which is critical for preventing delayed cracking in high-alloy overlay deposits.

Weld Metal Quality

The resulting weld deposits exhibit the following characteristics at 600-800 mm/min travel speed:

Parameter Conventional Flux (400 mm/min) Developed Flux (700 mm/min)
Hardness (HV) 220-260 215-255
Dilution (%) 8-12 10-15
Hydrogen content (mL/100g) <8 <6
Slag inclusion level (ASTM E45) 1.0-1.5 1.0-1.5
Arc stability rating Good Good
Slag removability Moderate Good

The slightly higher dilution at increased speed is expected due to the reduced heat input per unit length, which increases the relative contribution of base metal to the weld pool. However, the dilution remains within acceptable limits for most cladding applications where a minimum 1-2 mm overlay thickness is maintained.

Process Parameters and Flux Interaction

The flux performance is highly sensitive to the interaction with welding parameters. The following parameter windows have been identified as optimal for the developed flux:

Parameter Optimal Range Effect of Deviation
Travel speed 500-800 mm/min Below 500: excessive heat input, high dilution; Above 800: incomplete fusion, slag inclusions
Current density 8-12 A/mm² Below 8: poor arc stability; Above 12: excessive spatter, flux consumption
Strip thickness 3.0-4.0 mm Below 3.0: excessive burn-off rate; Above 4.0: poor slag interaction
Backing flux thickness 5-8 mm Below 5: inadequate slag cover; Above 8: excessive slag consumption, increased cost
Flux moisture content <0.5% Above 1.0%: hydrogen cracking, increased porosity

Engineering Practice Integration

The developed flux has been trialed in several industrial cladding applications:

Common Defects and Countermeasures

Defect Cause Countermeasure
Slag inclusion Insufficient slag fluidity at high speed Increase TiO2 to 6-8 wt%, ensure adequate backing flux thickness
Porosity High moisture content in flux Store flux in heated cabinets at 150-200°C, limit storage time to 24 hours
Undercut Excessive current density Reduce current density to 8-10 A/mm², increase travel speed
Cracking in overlay High hydrogen content, poor weldability Preheat base metal to 150°C, use low-hydrogen flux, apply PWHT at 600°C for 2 hours
Excessive dilution High heat input at low speed Increase travel speed to 600-700 mm/min, use backing ring to limit base metal melting

Study Insights and Implications

The development of a high-speed sintered flux for strip cladding represents a significant advancement in clad plate manufacturing productivity. The key insight is that flux design must be considered as an integrated system with the welding process parameters, not as a standalone consumable. The fluorite-silicate system with controlled basicity and alloy powder provides the necessary balance between slag fluidity, arc stability, and alloy transfer at elevated travel speeds.

From an engineering perspective, the transition to higher cladding speeds offers substantial economic benefits: a 700 mm/min speed compared to 400 mm/min represents a 75% productivity increase, translating directly to reduced manufacturing cost per square meter of clad plate. However, this productivity gain must be validated through rigorous qualification testing per NB/T 47014 or ASME IX, including weld tensile tests, bend tests, and overlay bond strength verification.

The literature also raises an important quality assurance consideration: at higher travel speeds, the window for parameter variation becomes narrower. The flux must be applied with greater consistency, and process monitoring (current, voltage, travel speed) must be more tightly controlled. This suggests that high-speed cladding operations should incorporate real-time parameter monitoring and automatic shutdown if parameters drift outside the qualified window.

In conclusion, the sintered flux development for high-speed strip cladding demonstrates that consumable engineering and process optimization are complementary disciplines that must be advanced together to achieve meaningful productivity improvements in clad plate manufacturing. Engineers should approach flux selection not merely as a consumable procurement decision but as a critical process engineering parameter that directly influences weld quality, productivity, and cost.